Explain how increasing the temperature of a reaction mixture increases the rate of reaction.

AQA A-Level Chemistry (7405) — 3.1.9 Rate equations (A-Level only) · Explain · 5 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (5 marks)

Increasing the temperature raises the kinetic energy of the reacting particles.

Higher kinetic energy means that, on average, particles move faster and therefore collide more often – the collision frequency increases.

With more energy, a larger proportion of the particles possess energy equal to or greater than the activation energy of the reaction.

Consequently, a greater number of collisions are successful, leading to more reaction events per unit time.

Thus, both the increased collision frequency and the larger fraction of collisions that exceed the activation energy combine to raise the overall rate of reaction.

Examiner tips

  • Use the word ‘explain’ to describe the chain of effects, not just state facts.
  • Show the link between temperature, kinetic energy, collision frequency and activation energy.
  • Mention both factors (frequency and energy proportion) to cover all marks.

Common mistakes

  • Only stating that temperature increases kinetic energy without linking to collision frequency or activation energy.
  • Using vague terms like ‘more energy’ without explaining the effect on collision success.
  • Failing to mention both the increased frequency and the greater proportion of energetic particles.

Mark scheme (5 marks)

  1. Increasing temperature increases the kinetic energy of particles
  2. Particles collide more frequently / there are more collisions per unit time
  3. A greater proportion of particles have energy greater than or equal to the activation energy
  4. Therefore more collisions are successful / result in a reaction
  5. Both the increased collision frequency AND the greater proportion exceeding activation energy contribute to a higher rate of reaction

Key terms in this question

rate of reaction

Related

More Rate equations (A-Level only) questions

▶ Try answering this question with AI marking (free) →