Propene is an alkene produced by cracking. Describe how propene could be identified using a chemical test, and explain why propene reacts in this way but propane does not. In your answer, refer to the bonding in both molecules.
Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).
Model answer (5 marks)
Add a drop of bromine water to each substance.
1. Propene: the orange colour of the bromine water disappears, becoming colourless.
2. Propane: the orange colour remains unchanged.
Propene is unsaturated, containing a C=C double bond. The π‑electrons are available for electrophilic addition of Br₂, breaking the double bond and forming 1,2‑dibromopropane, which removes the bromine colour. Propane is saturated, with only C–C and C–H single bonds; it has no π‑electrons and therefore cannot undergo electrophilic addition, so bromine water is not consumed.
1. Propene: the orange colour of the bromine water disappears, becoming colourless.
2. Propane: the orange colour remains unchanged.
Propene is unsaturated, containing a C=C double bond. The π‑electrons are available for electrophilic addition of Br₂, breaking the double bond and forming 1,2‑dibromopropane, which removes the bromine colour. Propane is saturated, with only C–C and C–H single bonds; it has no π‑electrons and therefore cannot undergo electrophilic addition, so bromine water is not consumed.
Examiner tips
- Use the exact phrase "add bromine water" and state the colour change for each compound.
- Explain that the double bond provides π‑electrons for electrophilic addition, whereas single bonds do not.
Common mistakes
- Saying that propane reacts with bromine water; it does not.
- Using vague terms like "unsaturated" without linking to the double bond and electrophilic addition.
Mark scheme (5 marks)
- Add bromine water to each substance / test with bromine water
- Propene decolourises / turns bromine water from orange to colourless
- Propane does not decolourise / has no effect on bromine water (remains orange)
- Propene is unsaturated / has a carbon–carbon double bond
- Propane is saturated / only has single bonds, so cannot react with bromine water / the double bond in propene makes it more reactive than propane
Key terms in this question
Related
- All AQA A-Level Chemistry (7405) revision notes →
- How to answer a "Describe and Explain" question →
- Decode the mark scheme abbreviations →
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