Propene is an alkene produced by cracking. Describe how propene could be identified using a chemical test, and explain why propene reacts in this way but propane does not. In your answer, refer to the bonding in both molecules.

AQA A-Level Chemistry (7405) — 3.3.4 Alkenes · Describe and Explain · 5 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (5 marks)

Add a drop of bromine water to each substance.
1. Propene: the orange colour of the bromine water disappears, becoming colourless.
2. Propane: the orange colour remains unchanged.
Propene is unsaturated, containing a C=C double bond. The π‑electrons are available for electrophilic addition of Br₂, breaking the double bond and forming 1,2‑dibromopropane, which removes the bromine colour. Propane is saturated, with only C–C and C–H single bonds; it has no π‑electrons and therefore cannot undergo electrophilic addition, so bromine water is not consumed.

Examiner tips

  • Use the exact phrase "add bromine water" and state the colour change for each compound.
  • Explain that the double bond provides π‑electrons for electrophilic addition, whereas single bonds do not.

Common mistakes

  • Saying that propane reacts with bromine water; it does not.
  • Using vague terms like "unsaturated" without linking to the double bond and electrophilic addition.

Mark scheme (5 marks)

  1. Add bromine water to each substance / test with bromine water
  2. Propene decolourises / turns bromine water from orange to colourless
  3. Propane does not decolourise / has no effect on bromine water (remains orange)
  4. Propene is unsaturated / has a carbon–carbon double bond
  5. Propane is saturated / only has single bonds, so cannot react with bromine water / the double bond in propene makes it more reactive than propane

Key terms in this question

alkene

Related

More Alkenes questions

▶ Try answering this question with AI marking (free) →