Ethene is a member of the alkenes homologous series. Describe the structure of ethene and explain why alkenes, unlike alkanes, can undergo addition reactions to form polymers.

AQA A-Level Chemistry (7405) — 3.3.4 Alkenes · Describe and Explain · 5 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (5 marks)

Ethene has the formula C₂H₄ and consists of two carbon atoms joined by a double bond, each carbon also bonded to two hydrogen atoms.

Because the C=C bond is a double bond, ethene is unsaturated. The π‑bond can be broken, allowing other atoms or molecules to add across the former double bond.

When many alkene monomers undergo such addition reactions, they link together to give a polymer chain.

Alkanes, in contrast, are saturated and contain only single C–C bonds; they have no π‑bond to break, so they cannot undergo addition reactions and therefore cannot polymerise in this way.

Examiner tips

  • Use the term ‘double bond’ and ‘unsaturated’ when describing the structure.
  • Explain that the π‑bond can be broken to allow addition. Mention that alkanes lack a double bond and are saturated.
  • Show the link between addition and polymerisation.
  • Keep the answer concise and use correct chemical terminology.

Common mistakes

  • Failing to mention the double bond or unsaturation. Confusing addition with substitution. Forgetting that alkanes are saturated and cannot add across a bond.

Mark scheme (5 marks)

  1. Ethene contains a carbon-carbon double bond
  2. Ethene / alkenes are unsaturated
  3. The double bond can open / break to allow other atoms / molecules to add on
  4. Many alkene monomers join together (to form a polymer)
  5. Alkanes are saturated / only have single bonds so cannot undergo addition reactions / cannot open a double bond

Key terms in this question

alkenes

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