Polymers are large molecules made up of monomers joined together by covalent bonds. Explain why polymers are solids at room temperature and why they do not conduct electricity.

Eduqas GCSE Chemistry — C2 Bonding, structure and properties · Explain · 4 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (4 marks)

Polymers have strong intermolecular forces such as van der Waals forces and, in some cases, hydrogen bonding, which hold the long chains together. These forces are large enough that a lot of energy is required to break them, so the melting point of most polymers lies above room temperature and they remain solid.

Polymers are covalently bonded chains that do not possess an overall electric charge. They lack free or delocalised electrons and there are no mobile ions present, so no charge carriers are available to move under an electric field. Consequently, polymers do not conduct electricity.

Examiner tips

  • Use the word ‘strong’ to describe the intermolecular forces and link this to the high melting point. Explain that covalent bonds give no free electrons or ions, which is why there is no conductivity.
  • Include both points in separate sentences for clarity and to show you understand the two separate reasons.

Common mistakes

  • Claiming polymers are liquids at room temperature. Saying polymers conduct electricity because they are large molecules. Forgetting to mention the lack of free electrons or ions.

Mark scheme (4 marks)

  1. Intermolecular forces between polymer molecules are relatively strong
  2. The strong intermolecular forces require a lot of energy to overcome, so the melting point is above room temperature / the polymer remains solid at room temperature
  3. Simple molecules / polymers do not have an overall electric charge
  4. There are no free / delocalised electrons (or ions) to carry the electrical charge / current

Key terms in this question

polymer · monomer · covalent bond

Related

More Bonding, structure and properties questions

▶ Try answering this question with AI marking (free) →