Graphite and diamond are both giant covalent structures made entirely of carbon atoms, yet they have very different properties. Explain why graphite can conduct electricity but diamond cannot, and why graphite is soft whilst diamond is very hard.

Eduqas GCSE Chemistry — C2 Bonding, structure and properties · Explain · 4 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (4 marks)

In graphite, each carbon atom uses three of its four valence electrons to form strong covalent bonds with three other carbons in the same plane, leaving one electron delocalised over the layer. This delocalised electron can move freely, allowing graphite to conduct electricity.

In diamond, every valence electron of each carbon atom is involved in a covalent bond with four neighbouring carbons. There are no free electrons, so diamond does not conduct electricity.

The layers in graphite are held together only by weak van der Waals forces, so they can slide over one another, giving graphite a soft, greasy feel.

In diamond, each carbon atom is tetrahedrally bonded to four others in all directions, forming a rigid, three‑dimensional network that resists deformation, making diamond extremely hard.

Examiner tips

  • Mention delocalised electrons for graphite conductivity
  • State no free electrons in diamond
  • Explain weak interlayer forces for softness
  • Highlight tetrahedral bonding for hardness

Common mistakes

  • Confusing graphite with diamond as having the same bonding
  • Forgetting to mention delocalised electrons
  • Over‑generalising the hardness of all covalent solids

Mark scheme (4 marks)

  1. In graphite, one electron from each carbon atom is delocalised (free to move), allowing it to carry charge / conduct electricity.
  2. In diamond, all four outer electrons of each carbon atom are used in covalent bonds, so there are no delocalised electrons to carry charge / conduct electricity.
  3. In graphite, there are no covalent bonds between the layers (only weak intermolecular forces), so the layers can slide over each other, making graphite soft.
  4. In diamond, each carbon atom forms four covalent bonds in all directions, creating a rigid, giant covalent structure that makes diamond very hard.

Key terms in this question

giant covalent structure

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