Explain why the voltage produced by a chemical cell depends on the type of chemicals used in the cell. In your answer, refer to what happens when the reactants in a non-rechargeable cell are used up.

AQA GCSE Chemistry (8462) — 4.5.2 Chemical cells and fuel cells (Chem only) · Explain · 4 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (4 marks)

A chemical cell contains two half‑cells that undergo redox reactions, creating a potential difference.
1. The voltage is determined by the standard electrode potentials of the two electrodes; different chemicals have different electrode potentials.
2. Therefore, a cell using a zinc–copper couple will give a different voltage to one using a silver–lead couple.
3. In a non‑rechargeable cell the reactions are not reversible; once the reactants are consumed the redox process cannot proceed in reverse.
4. When one reactant is used up the cell can no longer maintain a potential difference, so the voltage falls to zero.

Examiner tips

  • Use the phrase ‘standard electrode potential’ to show understanding of why different chemicals give different voltages.
  • Mention that the reaction is irreversible in a non‑rechargeable cell to justify the loss of voltage when reactants are depleted.

Common mistakes

  • Confusing the cell’s voltage with the amount of charge it can deliver.
  • Failing to state that the reaction cannot be reversed in a non‑rechargeable cell.

Mark scheme (4 marks)

  1. Cells contain chemicals which react to produce electricity / the chemical reaction produces a potential difference
  2. Different chemicals release different amounts of energy / produce different potential differences
  3. In a non-rechargeable cell the chemical reactions cannot be reversed
  4. The cell stops producing a potential difference / voltage when one of the reactants has been used up

Key terms in this question

chemical cell · non-rechargeable · reactants

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