Explain why the voltage produced by a chemical cell depends on the type of chemicals used in the cell. In your answer, refer to what happens when the reactants in a non-rechargeable cell are used up.
Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).
Model answer (4 marks)
A chemical cell contains two half‑cells that undergo redox reactions, creating a potential difference.
1. The voltage is determined by the standard electrode potentials of the two electrodes; different chemicals have different electrode potentials.
2. Therefore, a cell using a zinc–copper couple will give a different voltage to one using a silver–lead couple.
3. In a non‑rechargeable cell the reactions are not reversible; once the reactants are consumed the redox process cannot proceed in reverse.
4. When one reactant is used up the cell can no longer maintain a potential difference, so the voltage falls to zero.
1. The voltage is determined by the standard electrode potentials of the two electrodes; different chemicals have different electrode potentials.
2. Therefore, a cell using a zinc–copper couple will give a different voltage to one using a silver–lead couple.
3. In a non‑rechargeable cell the reactions are not reversible; once the reactants are consumed the redox process cannot proceed in reverse.
4. When one reactant is used up the cell can no longer maintain a potential difference, so the voltage falls to zero.
Examiner tips
- Use the phrase ‘standard electrode potential’ to show understanding of why different chemicals give different voltages.
- Mention that the reaction is irreversible in a non‑rechargeable cell to justify the loss of voltage when reactants are depleted.
Common mistakes
- Confusing the cell’s voltage with the amount of charge it can deliver.
- Failing to state that the reaction cannot be reversed in a non‑rechargeable cell.
Mark scheme (4 marks)
- Cells contain chemicals which react to produce electricity / the chemical reaction produces a potential difference
- Different chemicals release different amounts of energy / produce different potential differences
- In a non-rechargeable cell the chemical reactions cannot be reversed
- The cell stops producing a potential difference / voltage when one of the reactants has been used up
Key terms in this question
chemical cell · non-rechargeable · reactants
Related
- All AQA GCSE Chemistry (8462) revision notes →
- How to answer a "Explain" question →
- Decode the mark scheme abbreviations →
More Chemical cells and fuel cells (Chem only) questions
- A hydrogen fuel cell uses hydrogen and oxygen to produce a potential difference.…
- Compare rechargeable cells and non-rechargeable cells. Include in your answer ho…
- Explain why a non-rechargeable alkaline battery must be replaced once it stops w…
- Evaluate the use of hydrogen fuel cells compared to alkaline batteries as source…