Explain why hydrochloric acid is described as a strong acid, and why ethanoic acid is described as a weak acid. Include what is meant by the term 'weak acid' in your answer.

Eduqas A-Level Chemistry — 3.9 Acid-base equilibria · Explain · 5 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

A student has two solutions of equal concentration: one contains hydrochloric acid and the other contains ethanoic acid.

Model answer (5 marks)

Hydrochloric acid is a strong acid because it completely dissociates in water:

HCl → H⁺ + Cl⁻

All of the HCl molecules give H⁺ ions, so the concentration of H⁺ equals the initial concentration of HCl.

Ethanoic acid is a weak acid because it only partially dissociates:

CH₃COOH ⇌ CH₃COO⁻ + H⁺

An equilibrium is established between the undissociated acid and its ions, so only a fraction of the acid molecules produce H⁺.

A weak acid is therefore one that establishes such an equilibrium and does not give all of its H⁺ ions.

At the same concentration, the fully dissociated HCl provides a higher H⁺ concentration than the partially dissociated CH₃COOH.

Consequently, HCl has a lower pH than ethanoic acid when both are at equal concentrations.

Examiner tips

  • Show the full dissociation equation for HCl and the equilibrium for CH₃COOH. Mention the term ‘weak acid’ as ‘partial dissociation’. Compare the H⁺ concentrations and link to pH. Keep the answer concise to fit 5 marks.

Common mistakes

  • Writing that ethanoic acid is a ‘weak base’ or confusing ‘weak acid’ with ‘weak base’.
  • Failing to state that a weak acid establishes an equilibrium.

Mark scheme (5 marks)

  1. Hydrochloric acid completely/fully dissociates (ionises) in water
  2. Ethanoic acid only partially dissociates (ionises) in water
  3. A weak acid is one that partially dissociates / establishes an equilibrium between the dissociated and undissociated forms
  4. At equal concentrations, hydrochloric acid produces more hydrogen/H⁺ ions than ethanoic acid
  5. Therefore hydrochloric acid has a lower pH than ethanoic acid at the same concentration

Key terms in this question

strong acid · weak acid

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