A student dissolves the same number of moles of sulfuric acid and carbonic acid separately in equal volumes of water. Both solutions have the same concentration. Describe and explain the differences you would expect to observe in the pH values of the two solutions and in the rate at which each solution reacts with magnesium ribbon.

Eduqas A-Level Chemistry — 3.9 Acid-base equilibria · Describe and explain · 5 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Sulfuric acid is a strong acid. Carbonic acid is a weak acid.

Model answer (5 marks)

Sulphuric acid gives a lower pH than carbonic acid at the same concentration.

Sulphuric acid is a strong acid; it dissociates completely in water to give 2 H⁺ and SO₄²⁻, so the [H⁺] equals the acid concentration.

Carbonic acid is a weak acid; it only partially dissociates (H₂CO₃ ⇌ H⁺ + HCO₃⁻), so the [H⁺] is much lower than the acid concentration.

Because the [H⁺] is higher, the sulphuric acid solution reacts faster with magnesium ribbon. The high proton concentration gives a greater frequency of successful collisions between H⁺ and Mg, accelerating the reaction.

Thus the sulphuric acid solution has a lower pH and reacts more rapidly with magnesium than the carbonic acid solution.

Examiner tips

  • Use the terms ‘strong acid’ and ‘weak acid’ and state the degree of dissociation. Show that pH is related to [H⁺] and explain why a higher [H⁺] gives a lower pH. Mention the collision frequency argument for the reaction rate.
  • Keep the answer concise and use the exact terminology from the mark scheme.

Mark scheme (5 marks)

  1. Sulfuric acid has a lower pH than carbonic acid (at the same concentration)
  2. Sulfuric acid fully / completely dissociates (ionises) in water, producing a high concentration of hydrogen ions
  3. Carbonic acid only partially / incompletely dissociates (ionises), producing a lower concentration of hydrogen ions
  4. Sulfuric acid reacts faster with magnesium ribbon than carbonic acid does
  5. Because sulfuric acid has a higher concentration of hydrogen ions, giving a greater frequency of successful collisions with the magnesium

Key terms in this question

pH

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