Ethene can be converted into ethanol by two different methods: hydration with steam, and fermentation. Compare these two methods in terms of the conditions required and the type of process involved.

AQA GCSE Chemistry (8462) — 4.7.2 Reactions of alkenes and alcohols (Chem only) · Compare · 4 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (4 marks)

Hydration of ethene:
1. Requires high temperature and pressure (≈200 °C, 10–20 bar) and a catalyst (phosphoric acid).
2. Is carried out as a continuous process.
3. Gives ethanol directly, so the product is relatively pure.

Fermentation of ethene (via glucose):
1. Takes place at moderate or room temperature (≈25 °C) and atmospheric pressure.
2. Uses yeast (an enzyme system) as the catalyst.
3. Is a batch process.
4. Produces a dilute ethanol solution that must be concentrated by distillation.

Comparison: Hydration needs harsh conditions, a chemical catalyst and runs continuously, yielding pure ethanol; fermentation uses mild conditions, a biological catalyst, runs in batches and produces a dilute product that must be distilled.

Examiner tips

  • Use the word ‘compare’ to show similarities and differences; list each point clearly.
  • Mention temperature, pressure, catalyst, process type and product purity for each method.
  • Show the contrast in conditions and process type directly.
  • Include the need for distillation in fermentation.”]

Mark scheme (4 marks)

  1. Hydration requires a high temperature / high pressure (whereas fermentation does not / uses moderate/room temperature)
  2. Hydration uses a catalyst (phosphoric acid) whereas fermentation uses yeast / an enzyme
  3. Hydration is a continuous process whereas fermentation is a batch process
  4. Fermentation produces a dilute solution of ethanol (which must be concentrated / distilled) whereas hydration produces ethanol directly / in a purer form

Key terms in this question

hydration · fermentation

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