Ethanol can be produced by two different methods: fermentation of glucose, and the hydration of ethene. Compare these two methods of producing ethanol, including the raw materials used and the conditions required for each method.

Eduqas A-Level Chemistry — 2.4 Organic compounds · Compare · 5 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (5 marks)

Fermentation of glucose:
1. Raw material: glucose (sugar) derived from plants.
2. Catalyst: yeast (enzymes).
3. Conditions: low to moderate temperature (≈25–37 °C), anaerobic (no oxygen).
4. Product: dilute ethanol in aqueous solution – requires distillation to obtain pure ethanol.

Hydration of ethene:
1. Raw material: ethene, obtained from crude oil (non‑renewable).
2. Catalyst: acid (e.g. H₂SO₄) or phosphoric acid with a catalyst, often in a continuous process.
3. Conditions: high temperature and high pressure.
4. Product: relatively pure ethanol produced directly, no need for distillation.

Comparison:
- Fermentation uses renewable plant sugars; hydration uses non‑renewable ethene.
- Fermentation relies on biological enzymes; hydration uses chemical catalysts.
- Fermentation operates at mild temperatures and no oxygen; hydration requires high temperature and pressure.
- Fermentation yields a dilute solution needing distillation; hydration gives a more concentrated, purer ethanol directly.

Examiner tips

  • Mention renewable vs non‑renewable raw materials first.
  • State the catalyst type for each method.
  • Highlight the temperature/pressure differences.
  • Note the need for distillation in fermentation but not in hydration.

Common mistakes

  • Confusing the source of ethene with that of glucose.
  • Forgetting that fermentation is anaerobic.
  • Claiming hydration uses low temperature or no pressure.

Mark scheme (5 marks)

  1. Fermentation uses glucose / sugar (from plants) as the raw material, whereas hydration of ethene uses ethene (from crude oil / a non-renewable source).
  2. Fermentation uses yeast / enzymes to carry out the reaction.
  3. Fermentation requires a low / warm temperature (approximately 25–37 °C) and no oxygen / anaerobic conditions.
  4. Hydration of ethene requires a high temperature and high pressure.
  5. Fermentation produces a dilute solution of ethanol which must be distilled / concentrated, whereas hydration of ethene produces purer ethanol directly / in a continuous process.

Key terms in this question

fermentation · hydration · ethanol · ethene

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