Astatine is a halogen found below iodine in Group 7. Predict and explain the properties of astatine compared to iodine, including its reactivity and physical state at room temperature.

Edexcel GCSE Chemistry (1CH0) — 6.2 Group 7 · Predict and explain · 4 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Astatine is a very rare halogen at the bottom of Group 7. It is a radioactive element that is difficult to study, so scientists use trends in Group 7 to predict its properties.

Model answer (4 marks)

Astatine is less reactive than iodine because it has more electron shells; the outer shell is further from the nucleus, making it harder for astatine to gain an electron. Consequently, astatine has a higher boiling point than iodine and is a solid at room temperature, as boiling points increase down Group 7.

Examiner tips

  • State the trend in reactivity and explain it with electron shell distance.
  • Mention the higher boiling point and solid state, linking to the down‑group trend.

Common mistakes

  • Claiming astatine is more reactive than iodine.
  • Saying astatine is a gas or liquid at room temperature.
  • Ignoring the electron shell explanation for reactivity.

Mark scheme (4 marks)

  1. Astatine is less reactive than iodine
  2. Because astatine has more electron shells / the outer shell is further from the nucleus, so it is harder / less able to gain an electron
  3. Astatine has a higher boiling point than iodine / is a solid at room temperature
  4. Because boiling points increase down Group 7 / the trend in Group 7 is increasing boiling point going down the group

Key terms in this question

reactivity

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