A chemical cell stops producing a voltage after a period of time, whereas a hydrogen-oxygen fuel cell can continue to produce a voltage for as long as it is supplied with fuel. Explain the difference between how a chemical cell and a hydrogen-oxygen fuel cell produce a voltage, and why only one of them will eventually stop working.

Edexcel GCSE Chemistry (1CH0) — 5.4 Chemical cells and fuel cells (Chem only) · Explain · 4 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (4 marks)

A chemical cell uses two metal electrodes and an electrolyte to convert stored chemical energy into electrical energy. When the reactants at the electrodes (or the electrolyte) are consumed, the cell can no longer sustain the redox reaction and the voltage falls to zero.

A hydrogen‑oxygen fuel cell is also an electrochemical cell, but it is fed continuously with hydrogen and oxygen. The reaction H₂ + ½O₂ → H₂O takes place at the electrodes, producing a voltage as long as the gases are supplied.

Because the fuel cell’s only product is water, the reactants are not stored inside the cell; they are supplied from outside, so the cell does not run out of reactants and can keep working indefinitely.

Examiner tips

  • Use the word ‘electrodes’ and ‘electrolyte’ for a chemical cell; mention the redox reaction stops when reactants are used up. Use ‘continuously fed with H₂ and O₂’ and ‘only product is water’ for the fuel cell. Show the cause of stopping: depletion of reactants inside the cell.
  • Keep the answer concise – 4 points, one sentence per point.

Mark scheme (4 marks)

  1. A chemical cell converts chemical energy to electrical energy using two metal electrodes and an electrolyte
  2. The chemical cell stops producing a voltage when one of the reactants (electrode materials or electrolyte) is used up
  3. A hydrogen-oxygen fuel cell is an electrochemical cell that continuously produces a voltage as long as hydrogen and oxygen are supplied
  4. The only product of the hydrogen-oxygen fuel cell is water, so the reactants are not stored inside the cell and do not run out in the same way as a chemical cell

Key terms in this question

chemical cell · fuel cell · hydrogen-oxygen fuel cell · voltage

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