A chemical cell and a hydrogen-oxygen fuel cell can both be used to produce a voltage. Describe how a hydrogen-oxygen fuel cell works and explain one way in which it differs from a chemical cell in terms of how long it can continue to produce a voltage.

Edexcel GCSE Chemistry (1CH0) — 5.4 Chemical cells and fuel cells (Chem only) · Describe · 4 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (4 marks)

A hydrogen‑oxygen fuel cell is a device that is continuously fed with hydrogen gas at the anode and oxygen gas at the cathode.
1. At the anode the hydrogen is oxidised:

2H₂ → 4H⁺ + 4e⁻

The electrons travel through the external circuit to the cathode.
2. At the cathode the oxygen is reduced, combining with the electrons and the protons that have travelled through the electrolyte to form water:

O₂ + 4H⁺ + 4e⁻ → 2H₂O

The overall reaction is 2H₂ + O₂ → 2H₂O.
3. The flow of electrons through the external circuit gives a voltage.
4. Unlike a simple chemical cell, which stops producing voltage when its reactants are exhausted, a fuel cell can keep generating voltage as long as hydrogen and oxygen are supplied, because the reactants are not consumed in the cell itself but are continually fed in.

Examiner tips

  • Use the word "continuously" to show the supply of reactants. Mention the overall reaction 2H₂ + O₂ → 2H₂O. Explain the difference in terms of reactant supply. Use correct electrode terminology (anode, cathode).

Common mistakes

  • Confusing the roles of anode and cathode. Forgetting to state that water is the only product. Saying the fuel cell stops when reactants are used up, rather than when supply stops.

Mark scheme (4 marks)

  1. A hydrogen-oxygen fuel cell is continuously supplied with hydrogen (fuel) and oxygen
  2. Hydrogen donates electrons at one electrode and oxygen gains electrons at the other electrode
  3. Water is the only product of the hydrogen-oxygen fuel cell / overall reaction is 2H₂ + O₂ → 2H₂O
  4. A chemical cell stops producing voltage when one of the reactants is used up, whereas a fuel cell continues to produce a voltage as long as fuel and oxygen are supplied

Key terms in this question

chemical cell · fuel cell · hydrogen-oxygen fuel cell

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