Starch vs Cellulose: what's the difference?

A-Level Biology

Both are polysaccharides of glucose, but the glucose type and bonding make one a store and the other structural.

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Starch vs Cellulose — side by side

StarchCellulose
Monomerα-glucoseβ-glucose
Chain shapeCoiled/branched (amylose + amylopectin)Straight, unbranched
FunctionEnergy store in plantsCell-wall structure/strength
ArrangementCompact for storageParallel chains held by hydrogen bonds → microfibrils

Exam tip — how to tell them apart: α-glucose → starch (store). β-glucose → cellulose (structural). Alternate β-glucose units are flipped 180°, giving straight chains.

Common trap: Both are glucose polymers — the mark is for linking the α/β glucose and the bonding to the function.

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