Substance X has a melting point of 1083 °C and substance Y has a melting point of −39 °C. Using ideas about forces between particles, explain why these two substances have such different melting points.

Eduqas GCSE Chemistry — 2.1 Bonding, structure and properties · Explain · 4 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Substance X is a solid metal at room temperature. Substance Y is a liquid at room temperature.

Model answer (4 marks)

Substance X is a metal, so its atoms are held together by metallic bonds, which are strong and involve a delocalised sea of electrons.

Substance Y is a liquid at room temperature, so it must be a non‑metal or a weakly bonded compound; its particles are held together by much weaker van der Waals forces.

Because the melting point is the temperature at which the energy supplied is enough to overcome the forces between particles, the stronger metallic bonds in X require more energy to break, giving X a high melting point of 1083 °C.

In contrast, the weaker van der Waals forces in Y need far less energy to separate, so Y melts at only –39 °C.

Examiner tips

  • Use the term "metallic bonds" for X and "van der Waals forces" for Y. Explain that higher energy is required to break stronger bonds. Show the link between bond strength and melting point.
  • Make the comparison clear: X > Y in bond strength and melting point.

Common mistakes

  • Confusing ionic with metallic bonds for X. Using the wrong type of force for Y (e.g., saying it has ionic bonds). Failing to link bond strength to the energy needed to melt.

Mark scheme (4 marks)

  1. The amount of energy needed to change state depends on the strength of the forces between particles
  2. Substance X has stronger forces between its particles than substance Y
  3. More energy is needed to overcome the forces between particles in X, giving it a higher melting point
  4. Substance Y has weaker forces between its particles, so less energy is needed to separate them, giving it a much lower melting point

Key terms in this question

melting point · forces between particles

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