Nylon is a synthetic polymer used to make clothing and ropes. Explain why nylon is described as a polymer and outline the conditions needed to make nylon from its monomers.

OCR A-Level Chemistry B: Salters (H433) — PL Polymers and life · Explain · 5 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Nylon was one of the first synthetic polymers to be manufactured on a large scale. It is made by a condensation polymerisation reaction between two different monomers, each containing different functional groups. Unlike addition polymers, nylon releases a small molecule during its formation.

Model answer (5 marks)

A polymer is a large molecule made from many smaller molecules (monomers) joined together.
Nylon is produced by condensation polymerisation, not addition polymerisation.
During the reaction a small molecule – water – is released.
The two monomers are a diamine (–NH₂) and a dicarboxylic acid (–COOH).
An amide (–CO–NH–) bond, also called a peptide bond, links the monomers to give the nylon chain.

Examiner tips

  • Use the exact terms: polymer, condensation polymerisation, water, diamine, dicarboxylic acid, amide bond.
  • Show the sequence of points in the order of the mark scheme.
  • Keep each point brief – one sentence per point is enough for full marks.

Common mistakes

  • Confusing addition with condensation polymerisation.
  • Omitting the release of water or the specific functional groups of the monomers.

Mark scheme (5 marks)

  1. A polymer is a large molecule made from many smaller molecules (monomers) joined together
  2. Nylon is made by condensation polymerisation (not addition polymerisation)
  3. A small molecule (water) is released/eliminated during the reaction
  4. Two different monomers are used, one containing an amine (–NH₂) group and one containing a carboxylic acid (–COOH) group
  5. An amide (peptide) bond / –CO–NH– linkage forms between the monomers

Key terms in this question

polymer · monomer

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