Explain why the percentage yield of a reaction is almost always less than 100%, referring to at least two distinct reasons.

IB DP Chemistry Standard Level (2023 syllabus) — R2.1 How much? The amount of chemical change · Explain · 4 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (4 marks)

1. The reaction may be reversible or may not go to completion, so not all of the limiting reagent is converted into the desired product.
2. Side reactions or competing reactions can consume some of the reactants, producing by‑products instead of the target product.
3. During practical work the product can be lost in steps such as transferring, filtering or purifying, so the amount collected is less than the amount formed.
4. The theoretical yield is calculated assuming 100 % conversion of the limiting reagent, but real experimental conditions rarely achieve this ideal, so the actual yield is always lower.

Examiner tips

  • Use the exact terminology (e.g. ‘reversible’, ‘side reactions’, ‘product loss’).
  • Show the four distinct reasons, each as a separate point.
  • Keep the answer concise – no extra explanation beyond the four points.

Common mistakes

  • Mixing up the reasons (e.g. saying ‘product loss’ is the same as ‘side reactions’).
  • Using vague terms like ‘imperfect reaction’ instead of the specific reasons listed.

Mark scheme (4 marks)

  1. The reaction may be reversible / may not go to completion, so not all reactants are converted to products.
  2. Side reactions / competing reactions consume some of the reactants, producing by-products instead of the desired product.
  3. Product is lost during practical steps such as transferring, filtering, or purifying, reducing the amount collected.
  4. The theoretical yield assumes complete conversion of the limiting reagent to product, but real conditions rarely achieve this ideal.

Key terms in this question

percentage yield

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