Explain why simple molecular substances, such as chlorine, have low melting points.

AQA GCSE Chemistry (8462) — 4.2.2 How bonding and structure are related to the properties of substances · Explain · 4 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Chlorine exists as simple molecules. It is a gas at room temperature and pressure.

Model answer (4 marks)

Chlorine molecules are held together by weak intermolecular forces (London dispersion forces). These forces are very weak, so only a small amount of energy is required to overcome them. Consequently, the melting point is low. The covalent bonds within each Cl₂ molecule remain intact during melting.

Examiner tips

  • Use the word ‘intermolecular forces’ and specify London dispersion forces; mention they are weak.
  • Explain that only a small amount of energy is needed to break them.
  • State that covalent bonds stay intact – no breaking of intra‑molecular bonds.

Mark scheme (4 marks)

  1. Chlorine molecules are held together by intermolecular forces (between molecules)
  2. These intermolecular forces are weak
  3. Only a small amount of energy is needed to overcome / break these intermolecular forces
  4. The covalent bonds within the molecule are not broken during melting

Key terms in this question

simple molecular

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