Explain, using the kinetic model of an ideal gas, why two identical containers holding the same mass of gas but at different temperatures exert different pressures on their walls, and identify which container exerts the greater pressure.
Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).
Container A holds a fixed mass of ideal gas at 300 K. An identical container B holds the same mass of the same ideal gas at 600 K. Both containers have rigid walls and the same volume.
Model answer (4 marks)
At a given volume and amount of gas the pressure is proportional to the average kinetic energy of the molecules. In the kinetic model the average kinetic energy per molecule is ½mv² and is directly proportional to the absolute temperature (E_avg=3/2kT). Therefore the gas in container B, at 600 K, has a higher average kinetic energy and its molecules move faster than those in container A at 300 K.
Because the molecules in B move faster, each collision with a wall transfers a larger momentum change, giving a greater force per collision. Moreover, the higher speed means collisions occur more frequently per unit area per unit time. Both the larger force per collision and the higher collision frequency increase the pressure.
Thus, container B exerts the greater pressure on its walls, in accordance with Gay‑Lussac’s law (P∝T at constant V and n).
Because the molecules in B move faster, each collision with a wall transfers a larger momentum change, giving a greater force per collision. Moreover, the higher speed means collisions occur more frequently per unit area per unit time. Both the larger force per collision and the higher collision frequency increase the pressure.
Thus, container B exerts the greater pressure on its walls, in accordance with Gay‑Lussac’s law (P∝T at constant V and n).
Examiner tips
- Use the kinetic theory equation P=⅓ρv² or P=½ρv² to link temperature to pressure; mention both force per collision and collision frequency.
- State that B (600 K) has the higher pressure explicitly; this shows understanding of the proportionality P∝T.
Common mistakes
- Failing to mention that pressure depends on both collision frequency and force per collision; only citing one effect.
- Not identifying container B as the one with higher pressure, or confusing temperature with volume.
Mark scheme (4 marks)
- At higher temperature, gas molecules have greater average kinetic energy / move faster on average.
- Faster-moving molecules exert a greater force per collision on the container walls.
- Molecules also collide with the walls more frequently (per unit area per unit time) at higher temperature.
- Container B (at 600 K) exerts the greater pressure because pressure is proportional to absolute temperature at constant volume and fixed amount of gas (Gay-Lussac's / pressure law).
Key terms in this question
Related
- All IB DP Physics Higher Level (2023 syllabus) revision notes →
- How to answer a "Explain" question →
- Decode the mark scheme abbreviations →
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