Explain how rising atmospheric CO₂ concentrations affect the pH of the ocean and outline the consequences of this change for organisms with calcium carbonate structures.

IB DP Biology Higher Level (2023 syllabus) — D4.3 Climate change · Explain · 4 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (4 marks)

CO₂ dissolves in seawater forming carbonic acid (H₂CO₃). The acid dissociates, releasing H⁺ ions and lowering pH – this is ocean acidification.

The extra H⁺ reacts with carbonate ions (CO₃²⁻), decreasing their concentration.

Organisms that build calcium carbonate (CaCO₃) structures – such as corals, molluscs and echinoderms – find it harder to precipitate CaCO₃. Their shells or skeletons become weaker, growth slows and existing structures may dissolve.

Examiner tips

  • Show the CO₂→H₂CO₃→H⁺ sequence first; then link H⁺ to carbonate depletion; finally give specific organism examples and effects on CaCO₃.
  • Use the exact terms: ‘ocean acidification’, ‘carbonate ion’, ‘calcification’, ‘CaCO₃ structures’.
  • Keep answer concise – 4 marks, so one sentence per point.

Common mistakes

  • Mixing up CO₂ with O₂ or forgetting the acid dissociation step.
  • Using ‘acidification’ without explaining the H⁺/carbonate chemistry.
  • Mentioning organisms that do not rely on CaCO₃ (e.g. fish) or giving irrelevant effects.

Mark scheme (4 marks)

  1. CO₂ dissolves in seawater to form carbonic acid (H₂CO₃)
  2. Carbonic acid dissociates, releasing hydrogen ions (H⁺), lowering seawater pH — a process termed ocean acidification
  3. Excess H⁺ ions react with carbonate ions (CO₃²⁻), reducing carbonate ion concentration available for calcification
  4. Organisms such as corals, molluscs, and echinoderms struggle to form or maintain calcium carbonate (CaCO₃) shells/skeletons, leading to weaker structures, reduced growth, or dissolution of existing structures

Key terms in this question

calcium carbonate

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