Ethene is produced by cracking long-chain hydrocarbons. Ethene can be used as a monomer to make poly(ethene). Describe the process of addition polymerisation and explain why ethene, rather than ethane, is able to undergo this reaction.

AQA A-Level Chemistry (7405) — 3.3.8 Aldehydes and ketones (A-Level only) · Describe and Explain · 5 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (5 marks)

1. Addition polymerisation is a chain reaction in which many small molecules (monomers) join together to form a very large molecule – a polymer.
2. In this process the monomers link together without any small molecules being lost; the only product is the polymer.
3. Ethene has a carbon–carbon double bond, which makes it unsaturated.
4. The double bond opens (breaks) during the reaction, allowing the monomers to link together.
5. Ethane lacks a double bond, so its carbon–hydrogen bonds cannot open and it cannot undergo addition polymerisation.

Examiner tips

  • Use the term "chain reaction" for the mechanism. Mention that no small molecules are lost. Highlight the unsaturation of ethene. Explain the role of the double bond. State why ethane cannot polymerise.

Common mistakes

  • Confusing addition polymerisation with free‑radical polymerisation. Saying that a small molecule is lost. Forgetting to mention the unsaturation of ethene. Claiming ethane can polymerise because it is a hydrocarbon.

Mark scheme (5 marks)

  1. Addition polymerisation involves many small molecules (monomers) joining together
  2. To form a very large molecule / polymer
  3. No other product / no small molecule is lost in addition polymerisation
  4. Ethene has a carbon-carbon double bond (making it unsaturated)
  5. The double bond opens / breaks to allow monomers to link together, whereas ethane has no double bond so cannot polymerise

Key terms in this question

addition polymerisation · monomer · polymer

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