Ethanol can be used as a fuel and as a solvent. Describe how ethanol is produced by the hydration of ethene, and explain two reasons why this method may be preferred over fermentation for industrial fuel production.

AQA A-Level Chemistry (7405) — 3.3.5 Alcohols · Describe · 5 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (5 marks)

Ethanol is produced by the hydration of ethene:
1. Ethene (C₂H₄) reacts with steam (H₂O) in the presence of a catalyst.
2. The catalyst is phosphoric acid (H₃PO₄).
3. The reaction is carried out at high temperature (≈ 200 °C) and high pressure (≈ 10–15 bar) to drive the equilibrium toward ethanol.

This method is often preferred to fermentation for industrial fuel production because:
1. The hydration process gives a purer, higher‑quality ethanol, reducing downstream purification costs.
2. It is a continuous, fast, and controllable process that can be run at scale, whereas fermentation is slower, batch‑based and limited by the rate of microbial conversion of sugars.

Examiner tips

  • Use the exact reaction equation and mention catalyst, temperature and pressure; these are the key points. Show the two industrial advantages clearly and link them to purity and process control. Keep the answer concise and use the terminology from the mark scheme.

Common mistakes

  • Failing to mention the catalyst or the need for high temperature/pressure. Confusing the reaction with the reverse dehydration of ethanol. Not distinguishing between purity and process control as separate reasons.

Mark scheme (5 marks)

  1. Ethene reacts with steam (water) to produce ethanol
  2. A catalyst (phosphoric acid) is used
  3. High temperature and/or high pressure are required
  4. Hydration produces a purer / higher quality ethanol compared to fermentation (or continuous process so more efficient)
  5. Hydration uses ethene (a non-renewable petrochemical / from crude oil) whereas fermentation uses renewable sugar/glucose; so hydration gives a faster / more controllable rate of production

Key terms in this question

hydration · ethene · fermentation · ethanol

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