Ethanoic acid is a carboxylic acid found in vinegar. Explain why ethanoic acid is described as a weak acid, and describe two chemical reactions that show it behaves as an acid.
Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).
Model answer (5 marks)
Ethanoic acid is a weak acid because it only partially dissociates in water:
1.
CH₃COOH ⇌ CH₃COO⁻ + H⁺
Only a small fraction of the molecules ionise, so the concentration of H⁺ is low.
Two reactions that show its acidic behaviour:
2. With a metal such as magnesium:
2Mg + 2CH₃COOH → 2CH₃COO⁻Mg²⁺ + H₂↑
The acid donates H⁺ to the metal, forming a metal ethanoate salt and hydrogen gas.
3. With a carbonate (e.g. Na₂CO₃):
2CH₃COOH + Na₂CO₃ → 2CH₃COONa + H₂O + CO₂↑
The acid neutralises the carbonate, giving sodium ethanoate, water and carbon dioxide.
Both reactions involve the donation of H⁺ ions, demonstrating ethanoic acid’s behaviour as an acid.
1.
CH₃COOH ⇌ CH₃COO⁻ + H⁺
Only a small fraction of the molecules ionise, so the concentration of H⁺ is low.
Two reactions that show its acidic behaviour:
2. With a metal such as magnesium:
2Mg + 2CH₃COOH → 2CH₃COO⁻Mg²⁺ + H₂↑
The acid donates H⁺ to the metal, forming a metal ethanoate salt and hydrogen gas.
3. With a carbonate (e.g. Na₂CO₃):
2CH₃COOH + Na₂CO₃ → 2CH₃COONa + H₂O + CO₂↑
The acid neutralises the carbonate, giving sodium ethanoate, water and carbon dioxide.
Both reactions involve the donation of H⁺ ions, demonstrating ethanoic acid’s behaviour as an acid.
Examiner tips
- Use the exact dissociation equation to show partial ionisation
- Show the metal salt name (e.g. magnesium ethanoate) in the metal reaction
- Include the gas evolution (H₂, CO₂) to prove acid behaviour
- Mention H⁺ donation in both reactions
Common mistakes
- Writing the metal reaction without the salt product
- Forgetting to show the gas produced
- Using the wrong carbonate (e.g. CaCO₃) instead of a soluble carbonate
Mark scheme (5 marks)
- A weak acid is only partially dissociated (ionised) in water / does not fully ionise
- First chemical reaction described — reaction with a metal (e.g. magnesium/zinc/iron) producing hydrogen gas
- First reaction: also produces a salt (named or described as a metal ethanoate)
- Second chemical reaction described — reaction with a carbonate (or metal oxide/alkali/base) producing named products
- Both reactions linked to acid behaviour — identifies that H⁺ ions / protons are donated or that the acid is neutralised in both cases
Key terms in this question
Related
- All Eduqas A-Level Chemistry revision notes →
- How to answer a "Explain and Describe" question →
- Decode the mark scheme abbreviations →
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