Ethanoic acid is a carboxylic acid found in vinegar. Explain why ethanoic acid is described as a weak acid, and describe two chemical reactions that show it behaves as an acid.

Eduqas A-Level Chemistry — 2.7 Alcohols and carboxylic acids · Explain and Describe · 5 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (5 marks)

Ethanoic acid is a weak acid because it only partially dissociates in water:
1.
CH₃COOH ⇌ CH₃COO⁻ + H⁺
Only a small fraction of the molecules ionise, so the concentration of H⁺ is low.

Two reactions that show its acidic behaviour:
2. With a metal such as magnesium:
2Mg + 2CH₃COOH → 2CH₃COO⁻Mg²⁺ + H₂↑
The acid donates H⁺ to the metal, forming a metal ethanoate salt and hydrogen gas.

3. With a carbonate (e.g. Na₂CO₃):
2CH₃COOH + Na₂CO₃ → 2CH₃COONa + H₂O + CO₂↑
The acid neutralises the carbonate, giving sodium ethanoate, water and carbon dioxide.

Both reactions involve the donation of H⁺ ions, demonstrating ethanoic acid’s behaviour as an acid.

Examiner tips

  • Use the exact dissociation equation to show partial ionisation
  • Show the metal salt name (e.g. magnesium ethanoate) in the metal reaction
  • Include the gas evolution (H₂, CO₂) to prove acid behaviour
  • Mention H⁺ donation in both reactions

Common mistakes

  • Writing the metal reaction without the salt product
  • Forgetting to show the gas produced
  • Using the wrong carbonate (e.g. CaCO₃) instead of a soluble carbonate

Mark scheme (5 marks)

  1. A weak acid is only partially dissociated (ionised) in water / does not fully ionise
  2. First chemical reaction described — reaction with a metal (e.g. magnesium/zinc/iron) producing hydrogen gas
  3. First reaction: also produces a salt (named or described as a metal ethanoate)
  4. Second chemical reaction described — reaction with a carbonate (or metal oxide/alkali/base) producing named products
  5. Both reactions linked to acid behaviour — identifies that H⁺ ions / protons are donated or that the acid is neutralised in both cases

Key terms in this question

weak acid · carboxylic acid

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