Describe how bromine water can be used to distinguish between an alkane and an alkene, and explain why the two substances give different results.

Cambridge International IGCSE Chemistry (0620) — 11.5 Alkenes · Describe · 4 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (4 marks)

Bromine water is a dilute solution of Br₂ in water, giving an orange–brown colour. When an alkane is added, the solution remains orange–brown because alkanes are saturated hydrocarbons and do not react with Br₂. In contrast, when an alkene is added the orange–brown colour disappears and the solution becomes colourless. This decolourisation occurs because the C=C double bond in the alkene undergoes electrophilic addition with Br₂, forming a dibrominated alkane and consuming the bromine.

The different results are due to the presence of a carbon–carbon double bond in the alkene, which is reactive towards bromine, whereas the alkane has only single C–C bonds and is inert to bromine under these conditions.

Examiner tips

  • Mention the colour change of bromine water for each compound
  • Explain the role of the C=C bond in the reaction
  • State that alkanes are saturated and do not react

Common mistakes

  • Confusing the colour of bromine water with the colour of the alkene itself
  • Forgetting to mention that the alkane is saturated
  • Failing to explain that the double bond is the reactive site

Mark scheme (4 marks)

  1. Bromine water remains orange/brown with the alkane
  2. Bromine water is decolourised / turns colourless with the alkene
  3. The alkene contains a carbon–carbon double bond (C=C) which reacts with bromine
  4. The alkane is saturated / has no double bond, so it does not react with bromine water

Key terms in this question

bromine water · alkane · alkene

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