Catalytic cracking and steam cracking are two processes used to break down long-chain hydrocarbons. Describe both processes and explain why cracking is important to the petrochemical industry.

AQA A-Level Chemistry (7405) — 3.3.14 Organic synthesis (A-Level only) · Describe · 5 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (5 marks)

Catalytic cracking involves heating long‑chain hydrocarbons until they vapourise, then passing the vapour over a hot powdered aluminium oxide catalyst, which breaks the C–C bonds to give smaller alkanes and alkenes. Steam cracking mixes the hydrocarbon vapour with steam and heats it to a very high temperature, causing thermal cleavage of the chains to produce mainly alkenes and short‑chain alkanes. Cracking is important because the smaller molecules are useful as fuels and, especially the alkenes, serve as key feedstocks for the petrochemical industry to manufacture polymers and other chemicals.

Examiner tips

  • Use the exact terms ‘catalytic cracking’, ‘steam cracking’, ‘hydrocarbon vapour’, ‘powdered aluminium oxide’, ‘high temperature’, ‘alkenes’, ‘short‑chain alkanes’.
  • Explain the purpose of each step (vapourising, catalyst, steam, heat) and link products to fuels or polymer feedstocks.

Mark scheme (5 marks)

  1. Catalytic cracking: long-chain hydrocarbons are heated to vaporise them / turned into a gas
  2. Catalytic cracking: the vapour is passed over a hot powdered aluminium oxide catalyst
  3. Steam cracking: the hydrocarbon vapour is mixed with steam and heated to a very high temperature
  4. Cracking produces smaller, more useful molecules / produces alkenes and shorter-chain alkanes
  5. The products are important as fuels or as feedstock / alkenes are used to make polymers or other chemicals

Key terms in this question

catalytic cracking · steam cracking · cracking · hydrocarbons

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