Ammonia produced by the Haber process can be converted into nitric acid, which is then reacted with ammonia to form ammonium nitrate. Explain why ammonium nitrate is a suitable source of nitrogen for use in NPK fertilisers.

AQA GCSE Chemistry (8462) — 4.10.4 The Haber process and the use of NPK fertilisers (Chem only) · Explain · 4 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

NPK fertilisers improve agricultural productivity by supplying plants with essential elements. Nitrogen-containing compounds are a key component of these fertilisers.

Model answer (4 marks)

Plants require nitrogen for growth, so a nitrogen source is essential for fertilisers.
Ammonium nitrate is a nitrogen compound, providing nitrogen in both the ammonium (NH4+) and nitrate (NO3–) ions.
It is highly soluble in water, allowing it to be taken up by plant roots from the soil solution.
Its high nitrogen content (≈ 34 % N) means it supplies a large amount of nitrogen per unit mass, making it an efficient fertiliser.

Examiner tips

  • State the role of nitrogen for plants first. Mention both ions to show it is a nitrogen source. Highlight solubility and high nitrogen content. Use exact terminology (ammonium, nitrate, soluble).

Common mistakes

  • Forgetting to mention both NH4+ and NO3– as nitrogen sources. Claiming it is insoluble or underestimating its nitrogen content. Using vague terms like "good for plants" without linking to nitrogen uptake.

Mark scheme (4 marks)

  1. Plants need nitrogen to grow / nitrogen is an essential element for plant growth
  2. Ammonium nitrate contains nitrogen / is a nitrogen compound
  3. Ammonium nitrate is soluble (in water) / can be absorbed by plant roots (from soil solution)
  4. Ammonium nitrate has a high nitrogen content / provides nitrogen from two sources (ammonium ion and nitrate ion)

Key terms in this question

NPK fertilisers · ammonium nitrate · nitrogen · Haber process

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