Alkenes are produced during the cracking of crude oil fractions. Describe the differences between alkanes and alkenes, and explain why alkenes are considered more useful products of cracking than the long-chain alkane molecules they are made from.

Edexcel GCSE Chemistry (1CH0) — 8.1 Fuels · Describe and Explain · 4 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Model answer (4 marks)

Alkanes have the general formula CₙH₂ₙ₊₂ and are saturated hydrocarbons – all C–C bonds are single.
Alkenes have the general formula CₙH₂ₙ and contain at least one C=C double bond – they are unsaturated.
Alkenes are useful because the double bond can be reacted to give a wide range of products; they are the main monomers for polymers such as polyethylene and PVC, so there is a high industrial demand.
Long‑chain alkanes are less useful because they are very viscous and have high boiling points, making them poor fuels and difficult to transport; the smaller alkenes produced by cracking are easier to use as fuels or chemical feedstocks.

Examiner tips

  • Use the exact formulas CₙH₂ₙ₊₂ and CₙH₂ₙ; mention saturated vs unsaturated. Explain the double bond gives reactivity and polymerisation. Contrast viscosity/boiling point of long‑chain alkanes with demand for alkenes.
  • common_mistakes
  • :
  • Writing the wrong formula for alkenes (CₙH₂ₙ₊₂). Forgetting to mention the double bond or unsaturation. Not linking the double bond to polymerisation or industrial demand.

Mark scheme (4 marks)

  1. Alkanes have the general formula CₙH₂ₙ₊₂, whereas alkenes have the general formula CₙH₂ₙ
  2. Alkenes contain a carbon–carbon double bond / are unsaturated, whereas alkanes do not / are saturated
  3. Alkenes are used as monomers / to make polymers (plastics), so there is high industrial demand for them
  4. Long-chain alkanes are less useful / in less demand because they are too viscous / have too high a boiling point, whereas smaller molecules produced by cracking are in greater demand (e.g. as fuels or chemical feedstocks)

Key terms in this question

alkanes · alkenes · cracking

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