A student is preparing a sample of copper sulfate crystals in a school laboratory. They dissolve excess copper oxide in dilute sulfuric acid, then use an appropriate separation technique to obtain dry copper sulfate crystals from the resulting solution. Explain why crystallisation is the most appropriate separation technique to use in this situation, and describe how the student would carry out crystallisation to obtain dry copper sulfate crystals.

OCR A-Level Chemistry B: Salters (H433) — 2.2 Amount of substance · Explain · 5 marks · View as Markdown

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Copper sulfate is a soluble solid that can be obtained from its solution by removing the water solvent in a controlled way.

Model answer (5 marks)

Crystallisation is the most suitable method because copper(II) sulfate is a highly soluble solid that must be separated from the aqueous medium.

1. Dissolve the excess copper(II) oxide in dilute sulphuric acid to give a clear copper(II) sulfate solution.
2. Heat the solution in an evaporating dish until it becomes saturated and crystals begin to appear.
3. Allow the hot solution to cool slowly; as the temperature falls the solubility decreases and more crystals grow.
4. Once the solution is cold, filter the suspension to collect the crystals.
5. Pat the crystals dry with a paper towel or leave them to air‑dry at room temperature (or in a low‑temperature oven) until all water is removed.

Examiner tips

  • State that crystallisation separates a soluble solid from its solvent
  • Explain the heating–cooling cycle and why slow cooling gives larger crystals
  • Mention filtration and drying steps

Common mistakes

  • Using a filtration step before cooling, which gives few crystals
  • Failing to recognise that copper(II) sulfate is soluble and needs crystallisation
  • Leaving the crystals wet, giving a damp product

Mark scheme (5 marks)

  1. Crystallisation is appropriate because copper sulfate is a soluble solid (that needs to be separated from its solution / the water solvent)
  2. The solution is heated (in an evaporating dish) until crystals start to form
  3. Leave the solution to cool (slowly) so that more crystals form
  4. Filter the crystals from the remaining solution
  5. Pat dry / leave to dry at room temperature (or in a low-temperature oven) to obtain dry crystals

Key terms in this question

crystallisation

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