A heat engine operates between a hot reservoir at temperature T_H and a cold reservoir at temperature T_C. The engine performs one complete cycle. Explain why the thermal efficiency of this engine must always be less than 1, even if all mechanical components are frictionless.
Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).
A heat engine absorbs heat Q_H from a hot reservoir, does work W on the surroundings, and expels heat Q_C to a cold reservoir in each complete cycle.
Model answer (4 marks)
The second law of thermodynamics states that the total entropy of an isolated system cannot decrease. A heat engine is part of an isolated system together with the two reservoirs, so the entropy change of the engine plus reservoirs must be ≥ 0. Therefore some heat must always be transferred to the cold reservoir, i.e. Q_C > 0.
Because Q_C > 0, not all of the heat absorbed from the hot reservoir can be converted into work: W = Q_H – Q_C, so W < Q_H.
The thermal efficiency is defined as η = W/Q_H = 1 – Q_C/Q_H. Since Q_C/Q_H is a positive number, η must be less than 1.
The Carnot efficiency η_C = 1 – T_C/T_H gives the theoretical upper limit for any engine operating between T_H and T_C. For any finite T_C > 0, η_C < 1, which confirms that a 100 % efficient heat engine is impossible.
Examiner_tips: 1) Mention the second law and entropy increase. 2) Show the algebraic relation η = 1 – Q_C/Q_H. 3) State that Q_C > 0. 4) Reference Carnot efficiency as the upper bound.
Common_mistakes: 1) Forgetting that Q_C must be >0. 2) Confusing η = Q_H/W instead of W/Q_H. 3) Ignoring the Carnot limit and claiming η can reach 1 for some engines.
Because Q_C > 0, not all of the heat absorbed from the hot reservoir can be converted into work: W = Q_H – Q_C, so W < Q_H.
The thermal efficiency is defined as η = W/Q_H = 1 – Q_C/Q_H. Since Q_C/Q_H is a positive number, η must be less than 1.
The Carnot efficiency η_C = 1 – T_C/T_H gives the theoretical upper limit for any engine operating between T_H and T_C. For any finite T_C > 0, η_C < 1, which confirms that a 100 % efficient heat engine is impossible.
Examiner_tips: 1) Mention the second law and entropy increase. 2) Show the algebraic relation η = 1 – Q_C/Q_H. 3) State that Q_C > 0. 4) Reference Carnot efficiency as the upper bound.
Common_mistakes: 1) Forgetting that Q_C must be >0. 2) Confusing η = Q_H/W instead of W/Q_H. 3) Ignoring the Carnot limit and claiming η can reach 1 for some engines.
Mark scheme (4 marks)
- The second law of thermodynamics requires that the total entropy of an isolated system cannot decrease, so some heat must always be transferred to the cold reservoir.
- Because Q_C > 0 (heat must be expelled to the cold reservoir), not all of Q_H can be converted to work, so W < Q_H.
- Efficiency η = W/Q_H = 1 − Q_C/Q_H, and since Q_C/Q_H > 0, it follows that η < 1.
- The maximum possible efficiency is the Carnot efficiency η_C = 1 − T_C/T_H, which is less than 1 for any finite T_C > 0, confirming that a perfect (100% efficient) heat engine is thermodynamically impossible.
Key terms in this question
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