A chemist wants to separate ethanol from a mixture of ethanol and water. Explain why simple distillation is a suitable technique for separating this mixture, and describe the key steps involved in carrying out simple distillation.
Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).
Ethanol has a boiling point of 78 °C. Water has a boiling point of 100 °C.
Model answer (5 marks)
Simple distillation is suitable because ethanol and water have different boiling points.
1. The mixture is heated in a flask.
2. The liquid with the lowest boiling point, ethanol, evaporates first.
3. The ethanol vapour rises through the condenser.
4. The vapour is cooled and condenses back into a liquid.
5. The condensed liquid (ethanol) is collected in a separate receiver, leaving water behind in the distillation flask.
1. The mixture is heated in a flask.
2. The liquid with the lowest boiling point, ethanol, evaporates first.
3. The ethanol vapour rises through the condenser.
4. The vapour is cooled and condenses back into a liquid.
5. The condensed liquid (ethanol) is collected in a separate receiver, leaving water behind in the distillation flask.
Examiner tips
- Use the term ‘simple distillation’ and mention the boiling point difference. Show the sequence: heating → evaporation of ethanol → condensation → collection. Remember to state that water remains in the flask.
- common_mistakes
- :
- Confusing the order of steps (e.g., collecting before condensation). Using ‘fractional’ instead of ‘simple’ distillation. Failing to mention that ethanol has the lower boiling point.
Mark scheme (5 marks)
- Simple distillation is suitable because ethanol and water have different boiling points
- The mixture is heated and the liquid with the lowest boiling point (ethanol) evaporates first
- The ethanol vapour moves away from the solution
- The vapour is cooled and condensed back into a liquid
- The condensed liquid (ethanol) is collected separately, leaving water behind in the flask
Key terms in this question
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