A chemist is testing two liquid samples, X and Y, to find out whether each one is a pure substance or a mixture. The chemist heats both samples carefully and records the temperature at which each one boils. Sample X boils at a single, sharp temperature of 78 °C. Sample Y boils over a range of temperatures between 82 °C and 97 °C. Explain what these boiling point results tell the chemist about samples X and Y, and state one further test the chemist could carry out to confirm these conclusions.
Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).
Model answer (5 marks)
Sample X is a pure substance, because a pure substance boils at a single, sharp temperature.
Sample Y is a mixture, because a mixture boils over a range of temperatures.
To confirm this conclusion the chemist could carry out paper chromatography (or a melting‑point determination). A pure substance will give a single spot in all solvents (or a sharp melting point), whereas a mixture will give more than one spot (or a melting‑point range).
Sample Y is a mixture, because a mixture boils over a range of temperatures.
To confirm this conclusion the chemist could carry out paper chromatography (or a melting‑point determination). A pure substance will give a single spot in all solvents (or a sharp melting point), whereas a mixture will give more than one spot (or a melting‑point range).
Examiner tips
- Use the exact phrases ‘single, sharp temperature’ and ‘range of temperatures’ to match the mark scheme.
- Explain the reasoning for each sample before stating the test.
- Mention the test in one clear sentence, linking it to the evidence of purity or mixture.
- Keep the answer concise – 5 points can be covered in 4–5 short sentences.
Common mistakes
- Saying ‘Sample X is pure because it boils at 78 °C’ without mentioning the ‘single, sharp temperature’ phrase.
- Confusing the test with a qualitative analysis that doesn’t distinguish purity, e.g., just saying ‘tasting’ or ‘colour change’.
- Using a test that is not relevant to purity, such as a solubility test, which does not confirm the boiling‑point evidence.
Mark scheme (5 marks)
- Sample X is a pure substance
- Because pure substances boil at a single, sharp (specific) temperature
- Sample Y is a mixture
- Because mixtures boil over a range of temperatures
- Carry out paper chromatography (or melting point determination) — a pure substance produces a single spot in all solvents / has a sharp melting point, whereas a mixture produces more than one spot / melts over a range
Key terms in this question
pure substance · mixture · boiling point
Related
- All Eduqas A-Level Chemistry revision notes →
- How to answer a "Explain" question →
- Decode the mark scheme abbreviations →
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