A-Level Chemistry calculations & formulae

AQA / Edexcel / OCR A-Level Chemistry

The core calculations you must be fluent in for A-Level Chemistry, with the formula, what each term means and the units.

Written & reviewed by James Millett — Biology (Imperial College London), PGCE Science (University of Cambridge).

Amount of substance

In wordsSymbolsQuantities & units
moles = mass ÷ molar massn = m ÷ Mn (mol), m (g), M (g/mol)
moles = concentration × volumen = c × Vn (mol), c (mol/dm³), V (dm³)
moles of gas = volume ÷ molar volume (RTP)n = V ÷ 24 000V (cm³) at RTP; or ÷24 for dm³
ideal gas equationp V = n R Tp (Pa), V (m³), n (mol), R = 8.31, T (K)

Yield & atom economy

In wordsSymbolsQuantities & units
percentage yield = (actual ÷ theoretical) × 100% yield = actual/theoretical × 100mass or moles
atom economy = (Mr of desired product ÷ Mr of all reactants) × 100% atom economyfrom the balanced equation

Energetics & equilibria

In wordsSymbolsQuantities & units
enthalpy change = mass × specific heat capacity × temperature changeq = m c ΔTq (J), m (g), c (4.18 J/g°C), ΔT (°C)
pHpH = −log₁₀[H⁺][H⁺] in mol/dm³
hydrogen ion concentration[H⁺] = 10^(−pH)mol/dm³
Given vs recall: Constants such as the molar gas constant (R = 8.31 J/K/mol), molar volume at RTP (24 000 cm³/mol) and Avogadro’s constant are given in the data booklet — but you must know which formula to use and be able to rearrange it.
Exam tip: Always work in consistent units (dm³ vs cm³; g vs kg; °C vs K for gas laws) and quote the answer to the right number of significant figures.

▶ Practise a calculation question and get it marked (free) →

More equation references